Yes. Well, Clean and brighten, not strip. During construction, wood can get loaded with contaminants and/or mold spores. In addition, most ol based sealers prefer a deck properly pH balanced (leaning towards acidic)
Anything that will work well on concrete is usually strong enough to kill grass. The best best is to prewet all vegetation before you apply chems. On concrete a mix of butyl and sodium hydroxide works well.